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Magnetism and Ligand-Field Analysis ePub download

by M. Gerloch

  • Author: M. Gerloch
  • ISBN: 0521249392
  • ISBN13: 978-0521249393
  • ePub: 1114 kb | FB2: 1540 kb
  • Language: English
  • Category: Chemistry
  • Publisher: Cambridge University Press (February 24, 1984)
  • Pages: 607
  • Rating: 4.9/5
  • Votes: 408
  • Format: doc mbr doc mbr
Magnetism and Ligand-Field Analysis ePub download

by. M. Gerloch (Author).

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Magnetism and ligand-field analysis

Magnetism and ligand-field analysis. oceedings{AL, title {Magnetism and ligand-field analysis}, author {Malcolm Gerloch}, year {1983} }. Malcolm Gerloch. Ligand-Field Theory: 8. Tensor-operator theory 9. The ligand field 10. Techniques for parametric models 11. The nature of ligand-field theory and of th. ONTINUE READING.

The ligand-field formalism continues to succeed empirically and in cellular form provides chemically comprehensible representations of the electron . Cite this chapter as: Gerloch M. (1987) The Cellular Ligand-Field Model. In: Avery . Dahl .

The ligand-field formalism continues to succeed empirically and in cellular form provides chemically comprehensible representations of the electron distribution in transition-metal complexes. eds) Understanding Molecular Properties.

Magnetism and Ligand-Field Analysis. Cambridge University Press. Walmart 9780521109154. This button opens a dialog that displays additional images for this product with the option to zoom in or out. Tell us if something is incorrect. Magnetism and Ligand-Field Analysis.

Magnetism and Ligand-Field Analysis by M. Gerloch. Principles of Sedimentary Basin Analysis by Andrew D. Miall.

Ligand-field analyses of published ‘d–d’ transition energies, paramagetic susceptibilities, zero-field splittings, and g values in two series of transition-metal(III) complexes have been performed within the cellular ligand-field (. One series comprises the three-co-ordinated tris complexes of TiIII, VIII, CrIII, and FeIII.

Автор: Gerloch Название: Magnetism and Ligand-Field Analysis ISBN .

Описание: In this book, a synthesis of old and new notions straddling the disciplines of physics and chemistry is described. It offers a comparative analysis of models based on geometry versus those based on knowledge of the biological phenomenon.

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Ligand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes. It represents an application of molecular orbital theory to transition metal complexes. A transition metal ion has nine valence atomic orbitals - consisting of five nd, three (n+1)p, and one (n+1)s orbitals. These orbitals are of appropriate energy to form bonding interaction with ligands.

In this book, originally published in 1983, a synthesis of old and new notions straddling the disciplines of physics and chemistry is described; and this provides a means of exploiting ligan-field properties of transition-metal and lathanide complexes leading to a quantified chemical insight into the individual metal-ligand interactions in these molecular species. Electronic spectroscopy and the ESR technique are well documented, but there has long been a need for a thorough description of magnetochemistry. A major section of this book therefore provides a details account of the physics and chemistry of paramagnetism. The second main section is concerned with those aspects of ligand-field theory that are required to construct the working composite defining ligand-field analysis. Though the book is intended for the research chemist, the subject matter and level of some of the material is suitable for both advanced undergraduate and postgraduate chemists and solid-state physicists.
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